One-step synthesis of hierarchical [B]-ZSM-5 using cetyltrimethylammonium bromide as mesoporogen
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چکیده
منابع مشابه
One-Step Synthesis of Hierarchical ZSM-5 Using Cetyltrimethylammonium as Mesoporogen and Structure-Directing Agent
Hierarchical ZSM-5 zeolite is hydrothermally synthesized in a single step with cetyltrimethylammonium (CTA) hydroxide acting as mesoporogen and structure-directing agent. Essential to this synthesis is the replacement of NaOH with KOH. An in-depth solid-state NMR study reveals that, after early electrostatic interaction between condensed silica and the head group of CTA, ZSM-5 crystallizes arou...
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A new kind of organosilane (1,6-bis (diethyl(3-trimethoxysilylpropyl)ammonium) hexane bromide) with a geminitype structure was prepared and used as a mesoporogen for the synthesis of hierarchical porous ZSM-5 zeolite. There are two quaternary ammonium centers along with double hydrolysable -RSi(OMe)3 fragments in the organosilane, which results in a strong interaction between this mesoporogen a...
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Zeolite ZSM-5 presents a great source of interest in catalysis because of its shape selective properties. The absence of a relationship between the template size and shape of the structure generated during the synthesis of zeolites is illustrated by the case of ZSM-5. In this study, we have investigated the role of ethanol, methyltriphenylphosphonium bromide (MTPBr) and cetyltrimethylammonium b...
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zeolite zsm-5 presents a great source of interest in catalysis because of its shape selective properties. the absence of a relationship between the template size and shape of the structure generated during the synthesis of zeolites is illustrated by the case of zsm-5. in this study, we have investigated the role of ethanol, methyltriphenylphosphonium bromide (mtpbr) and cetyltrimethylammonium b...
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A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.
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ژورنال
عنوان ژورنال: TURKISH JOURNAL OF CHEMISTRY
سال: 2020
ISSN: 1303-6130
DOI: 10.3906/kim-2001-42